Skip to main content

Thermodynamics · Phase equilibrium and transitions

The binary lever rule is a component balance across a tie line

Problem

At fixed temperature and pressure, a nonreacting binary system separates into two equilibrium phases, $\alpha$ and $\beta$. Let $x$ denote the mole fraction of component 1. The endpoints of the relevant tie line are \[ x_\alpha=0.20,\qquad x_\beta=0.70, \] and a closed sample has overall composition $z=0.40$ and total amount $n=10.0\ \mathrm{mol}$. Let $f_\alpha=n_\alpha/n$ and $f_\beta=n_\beta/n$. 1. Starting only from the total-mole balance and the component-1 balance, derive formulas for $f_\alpha$ and $f_\beta$ in terms of $z,x_\alpha,x_\beta$. Do not quote the lever rule without deriving it. 2. Evaluate both phase fractions and both phase amounts for the stated sample. 3. Independently check the answer by inventorying component 1 in each phase and comparing the sum with the overall inventory. 4. Explain geometrically why the numerator for the $\beta$ fraction is the distance from $x_\alpha$ to $z$, not the distance from $z$ to $x_\beta$. State what happens at $z=x_\alpha$ and $z=x_\beta$, and why the two-phase formulas are not to be extrapolated to $z$ outside $[x_\alpha,x_\beta]$. Keep phase fractions distinct from the compositions inside each phase. This is a material-balance exercise on a supplied tie line, not a calculation of a Clapeyron coexistence slope or a van-der-Waals spinodal.

Hint

Write $n=n_\alpha+n_\beta$ and $nz=n_\alpha x_\alpha+n_\beta x_\beta$, then divide both equations by $n$.

Check your work

Work the problem yourself first. Then open it in Training to check your answer and read the full worked solution.

The answer check and full solution for this problem come with ProofAnvil Practice membership ($19 USD monthly). See membership. Or start with the free Thermodynamics sample problem: Try the free sample problem.

More Thermodynamics practice problems

Back to Thermodynamics

An original ProofAnvil practice problem, written for this course. ProofAnvil is a practice course, not a homework-answer service.